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Royal Society of Chemistry, Dalton Transactions, 23(42), p. 8188, 2013

DOI: 10.1039/c3dt50988e

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One-step assembly of Re(I) tricarbonyl 2-pyridyltetrazolato metallacalix[3]arene with aqua emission and reversible three-electron oxidation

This paper is available in a repository.
This paper is available in a repository.

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Abstract

The reaction of 2-pyridyltetrazolate with [Re(CO)5X] (X = Cl, Br) yielded the formation of an unexpected cyclic metallacalix[3]arene, as revealed by X-ray structural studies, characterised by aqua emission and reversible three-electron oxidation.