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Royal Society of Chemistry, Chemical Communications, 19(49), p. 1915

DOI: 10.1039/c2cc36741f

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Catalytic "triangles": Binding of iron in task-specific ionic liquids

Journal article published in 2013 by Denis Prodius ORCID, Fliur Macaev, Eugenia Stingaci ORCID, Vsevolod Pogrebnoi, Valeriu Mereacre, Ghenadie Novitchi, George E. Kostakis ORCID, Christopher E. Anson, Annie K. Powell
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Abstract

A new class of task-specific ionic liquids (ILs) which contain septuply positively charged {Fe(3)(III)O(RCOO)(6)L(3)}(7+) triangles has been synthesized and structurally characterized. Such metal-containing ILs can be repeatedly used as alternative catalysts in the synthesis of 2-pyrrolo-3'-yloxindole or the condensation of indoles with various aldehydes.