Published in
Royal Society of Chemistry, Chemical Communications, 19(49), p. 1915
DOI: 10.1039/c2cc36741f
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Catalytic "triangles": Binding of iron in task-specific ionic liquids
Journal article published in 2013 by
Denis Prodius 
,
Fliur Macaev,
Eugenia Stingaci ,
Vsevolod Pogrebnoi,
Valeriu Mereacre,
Ghenadie Novitchi,
George E. Kostakis ,
Christopher E. Anson,
Annie K. Powell
,
Fliur Macaev,
Eugenia Stingaci ,
Vsevolod Pogrebnoi,
Valeriu Mereacre,
Ghenadie Novitchi,
George E. Kostakis ,
Christopher E. Anson,
Annie K. Powell
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Abstract
A new class of task-specific ionic liquids (ILs) which contain septuply positively charged {Fe(3)(III)O(RCOO)(6)L(3)}(7+) triangles has been synthesized and structurally characterized. Such metal-containing ILs can be repeatedly used as alternative catalysts in the synthesis of 2-pyrrolo-3'-yloxindole or the condensation of indoles with various aldehydes.