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Royal Society of Chemistry, CrystEngComm, 1(16), p. 47-50, 2014
DOI: 10.1039/c3ce41785a
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An eight-connected porous metal–organic framework based on hetero pentanuclear clusters
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Abstract
A new MOF based on hetero pentanuclear clusters, [(CH3)2NH2]1.66[Cd1.84Na0.66(BDC)3]·DMF·0.5EtOH (1), has been prepared. Iodine adsorption studies reveal that 1 can reversibly adsorb iodine. Furthermore, electrochemical impedance spectroscopy (EIS) of 1⊃I2 shows that it has a relatively high conductivity at room temperature.