Published in
Royal Society of Chemistry, Chemical Communications, 27(50), p. 3612-3615, 2014
DOI: 10.1039/c4cc00690a
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The first case of an actinide polyrotaxane incorporating cucurbituril: A unique 'dragon-like' twist induced by a specific coordination pattern of uranium
Journal article published in 2014 by
Lei Mei,
Qun-Yan Wu,
Cai-Ming Liu 
,
Yu-Liang Zhao,
Zhi-Fang Chai,
Wei-Qun Shi
,
Yu-Liang Zhao,
Zhi-Fang Chai,
Wei-Qun Shi
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Abstract
In situ assembly of a cucurbituril-based pseudorotaxane and a uranyl nitrate precursor under hydrothermal conditions affords the first actinide polyrotaxane with a unique 'dragon-like' twist, which is induced by the specific coordination pattern of uranium and stabilized by hydrogen bonding between the η(1)-mode carboxylate group and adjacent methylene moieties of CB[6].