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Royal Society of Chemistry, Chemical Communications, 25(51), p. 5257-5260

DOI: 10.1039/c4cc08656b

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Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR

Journal article published in 2015 by Katrin Ackermann ORCID, Angeliki Giannoulis, David Bradford Cordes, Alexandra M. Z. Slawin, Bela E. Bode ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Pulsed electron paramagnetic resonance (EPR) spectroscopy is gaining increasing importance as a complementary biophysical technique in structural biology. Here, we describe the synthesis, optimisation, and EPR titration studies of a spin-labelled terpyridine Zn(II) complex serving as a small-molecule model system for tuneable dimerisation.