Published in
Royal Society of Chemistry, Chemical Communications, 24(47), p. 6918
DOI: 10.1039/c1cc12158h
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A linear single-molecule magnet based on [Ru(III)(CN)(6)](3-)
Journal article published in 2011 by
Kasper Steen Pedersen 
,
Jan Dreiser,
Joscha Nehrkorn,
Maren Gysler,
Magnus Schau-Magnussen,
Alexander Schnegg ,
Karsten Holldack,
Robert Bittl,
Stergios Piligkos,
Høgni Weihe,
Philip Tregenna-Piggott,
Oliver Waldmann,
Jesper Bendix
,
Jan Dreiser,
Joscha Nehrkorn,
Maren Gysler,
Magnus Schau-Magnussen,
Alexander Schnegg ,
Karsten Holldack,
Robert Bittl,
Stergios Piligkos,
Høgni Weihe,
Philip Tregenna-Piggott,
Oliver Waldmann,
Jesper Bendix
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Abstract
We report the synthesis, structure and magnetic properties of the first molecular cluster and single-molecule magnet to incorporate [Ru(III)(CN)(6)](3-). Frequency-domain Fourier-transform THz-EPR (FDFT THz-EPR) and magnetic susceptibility measurements indicate strongly anisotropic Mn-Ru exchange interactions.