Published in
Royal Society of Chemistry, Chemical Communications, 10(47), p. 2799, 2011
DOI: 10.1039/c0cc05029f
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A bright tetranuclear iridium(III) complex
Journal article published in 2011 by
Etienne Baranoff 
,
Enrico Orselli,
Lionel Allouche ,
Davide Di Censo,
Rosario Scopelliti,
Michael Grätzel,
Md Khaja Nazeeruddin,
M.-D. Khaja Nazeeruddin
,
Enrico Orselli,
Lionel Allouche ,
Davide Di Censo,
Rosario Scopelliti,
Michael Grätzel,
Md Khaja Nazeeruddin,
M.-D. Khaja Nazeeruddin
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Abstract
A cyclic tetranuclear cyclometallated iridium(III) complex using cyanide anions as bridging ligands and displaying a tetrahedrally distorted square geometry has been obtained with high yield; photo- and electrochemical characterizations show that most interesting properties of mononuclear cyclometallated iridium complexes are retained in the tetranuclear assembly.