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Royal Society of Chemistry, Chemical Communications, 29(48), p. 3539

DOI: 10.1039/c2cc17767f

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Ligand effects on the dimensionality of oxamato-bridged mixed-metal open-framework magnets

Journal article published in 2012 by Jesús Ferrando-Soria, Thais Grancha, Miguel Julve, Joan Cano, Francesc Lloret, Yves Journaux, Jorge Pasán ORCID, Catalina Ruiz-Pérez, Emilio Pardo
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This paper is available in a repository.

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Abstract

Increasing dimensionality [from 2D (1) to 3D (2)] and T(C) [from 10 (1) to 20 K (2)] in two new oxamato-bridged heterobimetallic Mn(II)(2)Cu(II)(3) open-frameworks result from the steric hindrance provided by the different alkyl substituents of the N-phenyloxamate bridging ligands.