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Royal Society of Chemistry, Chemical Communications, 72(50), p. 10376-10378, 2014

DOI: 10.1039/c4cc04189e

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Potential-driven molecular tiling of a charged polycyclic aromatic compound

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Using in situ electrochemical scanning tunnelling microscopy (EC-STM), we demonstrate fully reversible tuning of molecular tiling between self-assembled structures with supramolecular motifs containing 2, 3, 4, 6 or 7 tectons. The structures can be explained by electrocompression of the cationic adlayer at the solid-liquid interface.