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Royal Society of Chemistry, Chemical Communications, 3, p. 368-370, 2008

DOI: 10.1039/b715080f

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Solvatomagnetic effect and spin-glass behavior in a 1D coordination polymer constructed from EE-azido bridged MnIII3O units

Journal article published in 2008 by Cai-Ming Liu ORCID, De-Qing Zhang, Dao-Ben Zhu
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The non-uniform chain manganese(III) complex constructed from EE-azido bridged MnIII3O units, [MnIII3O(Brppz)3-(MeOH)3(N3)] 2MeOH [1, Brppz = 3-(5-bromo-2-phenolate)-pyrazolate], is the first example of 1D azido-bridged coordination polymer showing both solvatomagnetic effect and spin-glass behavior.