Published in
Royal Society of Chemistry, Chemical Communications, 16(48), p. 2213, 2012
DOI: 10.1039/c2cc16819g
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A robust zirconium N-heterocyclic carbene complex for the living and highly stereoselective ring-opening polymerization of rac-lactide
Journal article published in 2012 by
Charles Romain 
,
Benoît Heinrich,
Stéphane Bellemin Laponnaz,
Samuel Dagorne
,
Benoît Heinrich,
Stéphane Bellemin Laponnaz,
Samuel Dagorne
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Abstract
A readily accessible and robust Zr-NHC complex was found to polymerize rac-lactide in a highly controlled, living and stereoselective manner to afford heterotactic PLA.