Published in
Royal Society of Chemistry, Chemical Communications, 83(49), p. 9621, 2013
DOI: 10.1039/c3cc44859b
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Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8−
Journal article published in 2013 by
Salvador Cardona-Serra,
Juan M. Clemente-Juan,
Alejandro Gaita-Ariño,
Nicolas Suaud 
,
Ondrej Svoboda,
Eugenio Coronado
,
Ondrej Svoboda,
Eugenio Coronado
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Abstract
: The two-electron reduced mixed-valence polyoxometalate [GeV14O40](8-) presents an unusual paramagnetic behaviour as a consequence of the partial trapping of these electrons. The effect of applying an electric field is that of inducing antiferromagnetic coupling between the two delocalized electronic spins.