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Royal Society of Chemistry, Dalton Transactions, 44(41), p. 13568

DOI: 10.1039/c2dt31421e

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Single-ion magnet behaviour in [U(TpMe2)2I]

Journal article published in 2012 by Joana T. Coutinho ORCID, Maria A. Antunes, Laura C. J. Pereira ORCID, Hélène Bolvin ORCID, Joaquim Marçalo ORCID, Marinella Mazzanti, Manuel Almeida
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This paper is available in a repository.

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Abstract

[U(Tp(Me2))(2)I] exhibits at low temperatures single molecule magnet (SMM) behaviour comparable to its bipyridine derivative and related single ion U(iii) complexes recently reported as SMMs. The trend of variation of the energy barrier for the magnetic relaxation in these compounds is well reproduced by quantum chemistry calculations.