Published in
Royal Society of Chemistry, Chemical Communications, 84(51), p. 15438-15441, 2015
DOI: 10.1039/c5cc05713b
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An unusual chemoselective oxidation strategy by an unprecedented exploration of an electrophilic center of DMSO: a new facet to classical DMSO oxidation
Journal article published in 2015 by
Rajesh Chebolu,
Ashish Bahuguna,
Reena Sharma,
Vivek Kumar Mishra 
,
P. C. Ravikumar
,
P. C. Ravikumar
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Abstract
A conceptually new dimethyl sulfoxide (DMSO) based oxidation process without the use of any activator has been demonstrated for the oxidation of active methylenes and benzhydrols. The developed protocol involves reaction of electrophilic center of DMSO towards stabilized carbanions, which was unexplored before. Mechanistic investigation has confirmed that the source of oxygen is from DMSO