Published in
Royal Society of Chemistry, Chemical Communications, 7(50), p. 833-835
DOI: 10.1039/c3cc45791e
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Charge transfer-assisted self-limited decyanation reaction of TCNQ-type electron acceptors on Cu(100)
Journal article published in 2013 by
Christian Urban,
M. Ángeles Herranz 
,
Yang Wang,
Jonathan Rodríguez-Fernández,
Raúl García,
M. Ángeles Herranz,
Manuel Alcamí,
Nazario Martín ,
Fernando Martín ,
José M. Gallego,
Rodolfo Miranda,
Roberto Otero
,
Yang Wang,
Jonathan Rodríguez-Fernández,
Raúl García,
M. Ángeles Herranz,
Manuel Alcamí,
Nazario Martín ,
Fernando Martín ,
José M. Gallego,
Rodolfo Miranda,
Roberto Otero
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Abstract
TCNQ derivatives adsorbed on a metal surface undergo a self-limited decyanation reaction that only affects two out of the four cyano groups in the molecule. Combined Scanning Tunneling Microscopy/X-ray Photoelectron Spectroscopy experiments and Density Functional Theory calculations relate the self-limiting behavior to the transfer of electrons from the metal to the molecule.