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Royal Society of Chemistry, Chemical Communications, 80(50), p. 11829-11832, 2014

DOI: 10.1039/c4cc05545d

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Fingerprinting the tertiary structure of electroadsorbed lysozyme at soft interfaces by electrostatic spray ionization mass spectrometry

Journal article published in 2014 by Eva Alvarez de Eulate ORCID, Eva Alvarez de Eulate, Liang Qiao, Micheál D. Scanlon ORCID, Hubert H. Girault ORCID, Damien W. M. Arrigan
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Lysozyme can be electrochemically detected after adsorption at an electrified gel-water interface. Ex situ characterization by electrostatic spray ionization mass spectrometry provides insights into the interfacial detection mechanism by allowing changes to the tertiary structure of electroadsorbed lysozyme to be fingerprinted for the first time.