Royal Society of Chemistry, Chemical Communications, 44, p. 5803, 2008
DOI: 10.1039/b812297k
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Synthesis of poly( 2,2,2-trifluoroethyl methacrylate) by supported ATRP was investigated in supercritical carbon dioxide using a copper salt ligated to a polymeric ligand immobilised onto silica; after polymerisation, fluorinated polymers with well defined molecular weight and low polydispersity were obtained.