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Royal Society of Chemistry, Chemical Communications, 6, p. 598-600

DOI: 10.1039/b613655a

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Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation

Journal article published in 2007 by David R. Armstrong, William Clegg ORCID, Sophie H. Dale, David V. Graham, Eva Hevia ORCID, Lorna M. Hogg, Gordon W. Honeyman, Alan R. Kennedy, Robert E. Mulvey
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Benzene can be easily 1,4-dideprotonated stoichiometrically on reaction with two equivalents of a synergic mixture of tBu2Zn, NaTMP and TMEDA to give a unique 1,4-dizincated benzene product which has been characterised by X-ray crystallography and NMR spectroscopy as well as modelled theoretically by DFT computational studies; a related synergic dimagnesiation of benzene is also reported.