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Royal Society of Chemistry, CrystEngComm, 19(15), p. 3776, 2013
DOI: 10.1039/c3ce27056d
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Mixed Cu(II)–Bi(III) metal organic framework with a 2D inorganic subnetwork and its catalytic activity
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Abstract
The very dense (d = 4.359 g cm−3) three dimensional (3D) hybrid heterometallic framework Bi3O2Cu(OH)(pdc)2 (pdc3−:3,5-pyrazoledicarboxylate), 1, features a 2D inorganic subnetwork representing an unprecedented topological type, and is an effective catalyst for the diastereoselective synthesis of E-α,β-unsaturated ketones.