Royal Society of Chemistry, Green Chemistry, 8(16), p. 3741, 2014
DOI: 10.1039/c4gc00954a
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A computational methodology for designing ionic liquids (ILs) with an enhanced water absorption capacity to be used in absorption-refrigeration systems is presented here. It is based on increasing the hydrogen bond (HB)-acceptor ability of the anion and combining it with a cation that presents a weak cation-anion interaction. Employing this strategy, we identified and prepared three novel dianionic ILs with an enhanced water absorption capacity, larger than LiBr. ; This work was financed by national funding from Fundação para a Ciência e a Tecnologia (FCT), European Union, QREN, FEDER and COMPETE through the projects PTDC/QUI-QUI/ 121520/2010, PEst-C/CTM/LA0011/2013 and PEst-C/EQB/ LA0020/2013. Kiki A. Kurnia acknowledges FCT for the postdoctoral grant SFRH/BPD/88101/2012.