Published in
Royal Society of Chemistry, Chemical Communications, 84(49), p. 9785, 2013
DOI: 10.1039/c3cc44619k
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Mechanochemical and silica gel-mediated formation of highly electron-poor 1-cyanocarbonylferrocene
Journal article published in 2013 by
Daniel Nieto,
Sonia Bruña,
M. Merced Montero Campillo,
M. Merced Montero-Campillo,
Josefina Perles,
Ana Ma González-Vadillo,
Julia Méndez,
Otilia Mo 
,
Isabel Cuadrado
,
Isabel Cuadrado
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Abstract
Simple manual grinding of solid cyanomethylferrrocene () and silica gel provides a facile one-pot access route to prepare unexpected and highly electron-poor metallocene, 1-cyanocarbonylferrocene (). Electrochemical measurements supported by computational studies reveal that exhibits the highest Fe(II)/Fe(III) oxidation potential reported for mono-substituted ferrocenes.