Published in

Royal Society of Chemistry, Chemical Communications, 12(50), p. 1408-1410

DOI: 10.1039/c3cc47830k

Links

Tools

Export citation

Search in Google Scholar

Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation

Journal article published in 2013 by Mainak Mitra, Julio Lloret-Fillol, Matti Haukka, Miquel Costas ORCID, Ebbe Nordlander
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.