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Royal Society of Chemistry, Chemical Communications, 29(46), p. 5223

DOI: 10.1039/c0cc00779j

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Introduction of cavities up to 4 nm into a hierarchically-assembled metal-organic framework using an angular, tetratopic ligand

Journal article published in 2010 by Wenjuan Zhuang, Shengqian Ma ORCID, Shengqian, Xi-Sen Wang, Daqiang Yuan, Jian-Rong Li, Dan Zhao, Hong-Cai Zhou
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This paper is available in a repository.

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Abstract

Cavities up to 4 nm have been introduced into a hierarchically-assembled metal-organic framework by adopting an angular, semi-flexible tetratopic ligand. The resulting MOF possesses permanent porosity and exhibits stepwise sorption isotherms for O(2) and N(2) gases.