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Royal Society of Chemistry, Dalton Transactions, 12(44), p. 5284-5287

DOI: 10.1039/c5dt00196j

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Intramolecular N-coordination in ketiminoboranes

Journal article published in 2015 by Catherine Elizabeth Bacon, Liz Mansour, John J. Hayward, Jeremy Michael Rawson ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Treatment of the imine PhC(=NSiMe3)py with Et2BOMe or BF3•Et2O afforded bicyclic ketiminoboranes 4a and 4b via intramolecular N-coordination. The basicity of the imine N is evidenced by their reactivity towards Brønsted and Lewis acids and the structures of 4a•HCl and 4b•BF3 are reported as well as the dipyridyl imine derivative 4c•HCl.