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Royal Society of Chemistry, Chemical Communications, 96(50), p. 15191-15194

DOI: 10.1039/c4cc06693f

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Magnetic blocking in extended metal atom chains: A pentachromium(II) complex behaving as a single-molecule magnet

Journal article published in 2014 by A. Cornia ORCID, L. Rigamonti ORCID, S. Boccedi, R. Clérac, M. Rouzières, L. Sorace ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Compound [Cr5(tpda)4Cl2] (H2tpda = N(2),N(6)-di(pyridin-2-yl)pyridine-2,6-diamine), an Extended Metal Atom Chain complex featuring two quadruply-bonded {Cr2} units, exhibits field-induced slow relaxation of its magnetization arising from the terminal chromium(ii) ion and provides the first example of a chromium(ii)-based Single-Molecule Magnet.