Royal Society of Chemistry, New Journal of Chemistry, 9(27), p. 1301
DOI: 10.1039/b305929d
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Small phosphorus- modified molybdenum oxide clusters encapsulated inside the mesoporous channels of SBA-15 exhibit excellent catalytic performance for the partial oxidation of methane to formaldehyde with oxygen. A formaldehyde selectivity of 90% has been obtained at a single-pass methane conversion of 5.8%.