Royal Society of Chemistry, Dalton Transactions, 16(44), p. 7548-7553
DOI: 10.1039/c5dt00521c
Full text: Download
The preparation of copper(II) one-dimensional MOFs using an eco-efficient method is reported here. This method is based exclusively on using supercritical CO 2 as a solvent, without the addition of any other additive or co-solvent. Neutral acetylacetonate copper complexes and two linear linkers, namely, the bidentate 4,4¿-bipyridine and 4,4¿-trimethylenedipyridine molecules, were reacted under compressed CO 2 at 60 °C and 20 MPa for periods of 4 or 24 h. The success achieved in the synthesis of the different studied 1D-MOFs was related to the solubility of the reagents in supercritical CO 2 . The reaction yield of the synthesized coordination polymers via the supercritical route was close to 100% because both the reactants were almost completely depleted in the performed experiments. © The Royal Society of Chemistry 2015. ; This work was partially financed by EU COST project MP1202 OC-2011-2-10820 and by the Generalitat de Catalunya 2014SGR377. A. López-Periago acknowledges the RyC-2012- 11588 contract. We acknowledge support by the CSIC Open Access Publication Initiative through its Unit of Information Resources for Research (URICI) ; Peer Reviewed