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Royal Society of Chemistry, Chemical Communications, 1, p. 113-115, 2009

DOI: 10.1039/b817933f

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Gallyl lanthanide complexes containing unsupported Ln–Ga (Ln = Sm, Eu, Yb or Tm) bonds

Journal article published in 2009 by Cameron Jones, Andreas Stasch ORCID, William D. Woodul
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A series of bis(gallyl) lanthanide(ii) complexes, [Ln(II){Ga[(ArNCH)(2)]}(2)(tmeda)(2)] (Ln = Sm, Eu or Yb; Ar = C(6)H(3)Pr(i)(2)-2,6), and a gallyl thulium(iii) compound, [Tm(III){Ga[(ArNCH)(2)]}{(ArNCH)(2)}(tmeda)], have been prepared; the first structural studies of Ga-Tm and Ga-Sm bonded complexes are described.