Published in
Royal Society of Chemistry, Chemical Communications, 10(47), p. 2814
DOI: 10.1039/c0cc05054g
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Molecular recognition of ADP over ATP in aqueous solution by a polyammonium receptor containing a pyrimidine residue
Journal article published in 2011 by
Paloma Arranz Mascaros,
Carla Bazzicalupi 
,
Antonio Bianchi,
Claudia Giorgi,
M. Dolores Gutiérrez Valero,
M. Dolores Gutiérrez Valero,
Rafael López Garzón,
M. Luz Godino Salido,
M. Luz Godino Salido ,
Barbara Valtancoli
,
Antonio Bianchi,
Claudia Giorgi,
M. Dolores Gutiérrez Valero,
M. Dolores Gutiérrez Valero,
Rafael López Garzón,
M. Luz Godino Salido,
M. Luz Godino Salido ,
Barbara Valtancoli
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Abstract
The synergistic action of the different binding groups of the polyfunctional HL receptor leads to the recognition of ADP over ATP in water, with a selectivity coefficient of up to 116, a phenomenon which is unprecedented in the context of synthetic receptors in water. The recognition is mostly due to the good matching between H(3)L(2+) and the protonated forms of ADP.