Published in
Royal Society of Chemistry, Chemical Communications, 2(49), p. 158-160, 2013
DOI: 10.1039/c2cc37036k
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Relaxations in heterolanthanide dinuclear single-molecule magnets
Journal article published in 2012 by
Ji-Dong Leng,
Jun-Liang Liu 
,
Yan-Zhen Zheng,
Liviu Ungur ,
Liviu F. Chibotaru,
Fu-Sheng Guo,
Ming-Liang Tong
,
Yan-Zhen Zheng,
Liviu Ungur ,
Liviu F. Chibotaru,
Fu-Sheng Guo,
Ming-Liang Tong
This paper is available in a repository.
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Abstract
A heterospin dinuclear complex [Dy(0.87)Yb(1.13)(H(2)cht)(2)Cl(4)(H(2)O)(MeCN)]·MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy(2) and Yb(2) isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.