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Royal Society of Chemistry, CrystEngComm, 8(15), p. 1524-1527

DOI: 10.1039/c2ce26487k

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Targeted synthesis of a mesoporous triptycene-derived covalent organic framework

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This paper is available in a repository.

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Abstract

The synthesis and characterization of a highly porous triptycene-derived covalent organic framework (TDCOF-5) and its performance in small gas storage are reported. TDCOF-5 crystallizes into a 2D mesoporous network that contains accessible boron sites, exhibits high surface area (SALang = 3832 m2 g-1), and high gas uptake under low pressure settings.