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Royal Society of Chemistry, Chemical Communications, 9(48), p. 1287-1289

DOI: 10.1039/c2cc16221k

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A novel high-spin tridecanuclear NiIIcluster with an azido-bridged core exhibiting disk-like topology

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A high-spin tridecanuclear Ni(II) cluster, [Ni(II)(13)(N(3))(18)(dpo)(4)(Hdpo)(2)(H(2)hpo)(4)(H(2)O)(MeOH)] [Ni(II)(13)(N(3))(18)(dpo)(4)(Hdpo)(2)(H(2)hpo)(4)(H(2)O)(2)] (1) (Hdpo = 1-(dimethylamino)propan-2-one oxime and H(2)hpo = 1-(hydroxyamino)propan-2-one oxime) with a purely azido-bridged core, is reported with dominant ferromagnetic coupling between Ni(II) ions. The latter molecule exhibits a unique planar core topology with the largest N(3)(-):Ni(II) ratio reported to date.