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Royal Society of Chemistry, Journal of the Chemical Society, Chemical Communications, 10, p. 872

DOI: 10.1039/c39930000872

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A novel 2,18-bridged biliverdin derivative

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Base-catalysed dehydrohalogenation of a 3,18-bis(2-ohloroethyl)biliverdin 1 affords a novel 3-vinylbiliverdin 3 in which the 2- and 18-positions are bridged with a propano-tether; the structure of 3 has been established using single crystal X-ray and 1H nuclear Overhauser effect studies.