Published in
Royal Society of Chemistry, Chemical Communications, 14(47), p. 4243, 2011
DOI: 10.1039/c0cc05837h
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Functionalization of the corrole ring: The role of isocorrole intermediates
Journal article published in 2011 by
Luca Tortora,
Sara Nardis,
Frank R. Fronczek,
Kevin M. Smith,
Roberto Paolesse 
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Abstract
Bromination of 3-nitro-5,10,15-triarylcorrole selectively provides two regioisomers, depending on the reaction pathway. An isocorrole species is the key intermediate to drive the reaction towards the 2-Br-17-nitro regioisomer.