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Royal Society of Chemistry, Dalton Transactions, 16(44), p. 7109-7113, 2015

DOI: 10.1039/c5dt00346f

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Molecular and Electronic Structures of Donor-Functionalized Dysprosium Pentadienyl Complexes

Journal article published in 2015 by Benjamin Morgan Day ORCID, Nicholas F. Chilton ORCID, Richard Alan Layfield ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Two dysprosium complexes, [(C5H4Me)2Dy(L1)] (3) and [(L1)Dy(μ-Cl)3{Li(tmeda)}]2 (4), with amino-functionalized pentadienyl ligands L1 are described. Crystallographic studies of 3 and 4 show that the pendant amino group influences the pentadienyl conformation and the ligand hapticity. Electronic structure calculations reveal that L1 has a strong influence on the orientation of the main magnetic axis of the ground Kramers doublets in 3 and 4.