Published in

Elsevier, Materials Science in Semiconductor Processing, 4-5(9), p. 589-596

DOI: 10.1016/j.mssp.2006.08.062

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A comparative study of ion implantation and irradiation-induced defects in Ge crystals

Journal article published in 2006 by V. P. Markevich ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The possibility of making devices which use the high charge carrier mobility of Ge in mainstream semiconductor technology has drawn attention to the very limited understanding of ion implantation damage in germanium and the defect reactions associated with its removal. Results of DLTS and high-resolution Laplace DLTS measurements of defects induced in n-type Ge and dilute Ge-rich SiGe by irradiations with 1–6 MeV electrons are presented in this work. The ensuing defect reactions that occur during annealing are discussed. This is compared with damage induced by 1–3 MeV Si or Ge ion implantations into Ge and SiGe at low and high doses and its subsequent removal by furnace annealing.After electron irradiation a sequence of point defects was generated, the detailed spectrum of which depended on the impurity content of the material. In oxygen lean Ge the DLTS spectrum was dominated by the E-center (vacancy–group-V-impurity atom pair). In oxygen-rich material the V–O pair was the center present in the greatest concentration. The annealing kinetics of the observed centers are reported. The situation in ion-implanted material is more complex. It is often not possible to measure the as-implanted material with DLTS due to carrier removal and, in some cases, type conversion. DLTS spectra of the high-dose-implanted samples after annealing show evidence of broader features characteristic of defect clusters. The evolution of these defects with annealing is discussed in the context of known defect reactions. Because diffusion of dopant species in Ge is thought to be vacancy mediated the focus of this analysis is on vacancy-related clusters.