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Royal Society of Chemistry, Chemical Communications, 18, p. 2538

DOI: 10.1039/b822678d

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A new family of metallaboratrane complexes based on 7-azaindole: B-H activation mediated by carbon monoxide

Journal article published in 2009 by Nikolaos Tsoureas, Mairi F. Haddow ORCID, Alex Hamilton, Gareth R. Owen
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl)(3)}(-)] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.