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Royal Society of Chemistry, Chemical Communications, 31(50), p. 4059-4061, 2014

DOI: 10.1039/c3cc48935c

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A chiral spin crossover metal–organic framework

Journal article published in 2014 by Wei Liu, Xin Bao, Ling Mao, Jiri Tucek ORCID, Radek Zboril ORCID, Jun-Liang Liu ORCID, Fu-Sheng Guo, Zhao-Ping Ni, Ming-Liang Tong
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This paper is available in a repository.

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Abstract

A chiral metal-organic framework exhibiting spin crossover (SCO) property, [Fe(II)(mptpy)2]·EtOH·0.2DMF (·solv), has been solvothermally synthesized through spontaneous resolution. It displays remarkable stability and two-step SCO at (Tc1 = 200 K) and above (Tc2 = 357 K) room temperature.