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Royal Society of Chemistry, Dalton Transactions, 14(44), p. 6340-6342

DOI: 10.1039/c5dt00481k

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A CH2Cl2complex of a [Rh(pincer)]+cation

Journal article published in 2015 by Gemma M. Adams, F. Mark Chadwick, Sebastian D. Pike ORCID, Andrew S. Weller
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The CH2Cl2 complex [Rh((tBu)PONOP)(κ(1)-ClCH2Cl)][BAr(F)4] is reported, that also acts as a useful synthon for other complexes such as N2, CO and H2 adducts; while the analogous PNP complex undergoes C-Cl activation.