Published in
Royal Society of Chemistry, Chemical Communications, 16(50), p. 1937, 2014
DOI: 10.1039/c3cc48228f
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Porous organic polymers with anchored aldehydes: A new platform for post-synthetic amine functionalization en route for enhanced CO2 adsorption properties
Journal article published in 2014 by
Vincent Guillerm,
Lukasz J. Weseliński,
Mohamed H. Alkordi 
,
M. Infas H. Mohideen,
Youssef Belmabkhout,
Amy J. Cairns,
Mohamed Eddaoudi
,
M. Infas H. Mohideen,
Youssef Belmabkhout,
Amy J. Cairns,
Mohamed Eddaoudi
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Abstract
A novel porous organic polymer has been synthesized using the molecular building block approach to deliberately encompass aldehyde functionalities amenable to post functionalization. The resultant porous framework allows a facile, one-step quantitative and post-synthetic functionalization by amines, permitting enhanced CO2 sorption properties.