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Royal Society of Chemistry, Dalton Transactions, 41(43), p. 15287-15290, 2014

DOI: 10.1039/c4dt02359e

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Avoiding problem reactions at the ferrocenyl-alkyne motif: A convenient synthesis of model, redox-active complexes for molecular electronics

Journal article published in 2014 by Michael Stephen Inkpen ORCID, Andrew J. P. White, Tim Albrecht, Nicholas J. Long
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A much improved route to 1,1′-bis(arylethynyl)ferrocenes comprising accessible thiolates on the aryl ring is reported. Unanticipated reactions between AcCl, TBAF–BBr3 and ferrocenyl-alkynes are also discussed, offering a rationale for previous synthetic difficulties.