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Royal Society of Chemistry, Dalton Transactions, 34(44), p. 15079-15082

DOI: 10.1039/c4dt03184a

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Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

Journal article published in 2015 by David J. Harding ORCID, Wasinee Phonsri, Phimphaka Harding ORCID, Keith S. Murray, Boujemaa Moubaraki, Guy N. L. Jameson
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This paper is available in a repository.

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Abstract

[Fe(qsal-Br)2]NO3·2MeOH is reported which undergoes abrupt two step symmetry breaking spin crossover, T½(1st step) = 136 K and T½(2nd step) = 232 K with a hysteresis of 16 K and 5 K, respectively and an unprecedented [HS-LS] plateau of 96 K