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Royal Society of Chemistry, Chemical Communications, 37(47), p. 10233

DOI: 10.1039/c1cc12852c

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A one-dimensional coordination polymer exhibiting simultaneous spin-crossover and semiconductor behaviour

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This paper is available in a repository.

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Abstract

NSFC [90922031, 20821001]; "973 Program'' [2007CB815302] ; A rare organosulfur one-dimensional coordination polymer, [Co(C(9)H(6)NS)(2)], was synthesized by the reaction between the 8-mercaptoquinoline and cobalt acetate salts in EtOH, which shows strong magnetic coupling and the presence of spin-glassy and spin-crossover phenomena with simultaneous semiconductor behaviour.