Royal Society of Chemistry, Chemical Communications, 43(47), p. 11867, 2011
DOI: 10.1039/c1cc15175d
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A new zeotype titanium silicate oxidation catalyst with the STT topology has been synthesized from direct synthesis. Ti-STT has a microporous structure with small pore openings, allowing shape selective oxidation catalysis. The isomorphous substitution of Si by Ti in the framework has been confirmed by Raman, FT-IR, UV-VIS and XANES spectroscopies.