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Royal Society of Chemistry, Analyst, 6(130), p. 828

DOI: 10.1039/b502514a

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Significant viscosity dependent deviations from classical van Deemter theory in liquid chromatography with porous silica monolithic columns

Journal article published in 2005 by Pn Nesterenko, Marina A. Rybalko, Brett Paull ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Significant deviations from classical van Deemter behaviour, indicative of turbulent flow liquid chromatography, has been recorded for mobile phases of varying viscosity on porous silica monolithic columns at elevated mobile phase flow rates.