Published in
Royal Society of Chemistry, Chemical Communications, 34(47), p. 9666, 2011
DOI: 10.1039/c1cc12569a
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Little exchange at the liquid/solid interface: Defect-mediated equilibration of physisorbed porphyrin monolayers
Journal article published in 2011 by
Michiel J. J. Coenen,
Melissa Cremers,
Duncan den Boer,
Fieke J. van den Bruele,
Duncan den Boer,
F. J. van den Bruele,
Tony Khoury,
Maxine Sintic,
Maxwell J. Crossley 
,
Willem J. P. van Enckevort,
W. J. P. van Enckevort,
Bas L. M. Hendriksen,
Johannes A. A. W. Elemans,
Sylvia E. Speller
,
Willem J. P. van Enckevort,
W. J. P. van Enckevort,
Bas L. M. Hendriksen,
Johannes A. A. W. Elemans,
Sylvia E. Speller
This paper is available in a repository.
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Abstract
The transition from low to high density 2D surface structures of copper porphyrins at a liquid/solid interface requires specific defects at which nearly all exchange of physisorbed molecules with those dissolved in the supernatant occurs.