Published in
Royal Society of Chemistry, Chemical Communications, 44(48), p. 5479, 2012
DOI: 10.1039/c2cc31443f
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Asymmetric H-D exchange reactions of fluorinated aromatic ketones
Journal article published in 2012 by
Yujun Zhao,
XiaoZhi Lim,
Yuanhang Pan,
Lili Zong,
Wei Feng,
Choonhong-H. Tan,
Kuo-Wei Huang 
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Abstract
Chiral bicyclic guanidine catalyzes the asymmetric H-D exchange reactions. Up to 30% ee was achieved. DFT calculations were employed to elucidate and explain the origin of the reaction's stereoselectivity. © 2012 The Royal Society of Chemistry.