Published in
Royal Society of Chemistry, Chemical Communications, 10(48), p. 1508-1510, 2012
DOI: 10.1039/c1cc14643b
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Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides
Journal article published in 2012 by
Richard A. Layfield 
,
Scott A. Layfield R. A. Tuna F. Wernsdorfer W. Winpenny R. E. P. Sulway,
Floriana Tuna,
Wolfgang Wernsdorfer,
Richard E. P. Winpenny,
R. A. Layfield F Tuna W Wernsdorfer and R. E. P. Winpenny S. Sulway
,
Scott A. Layfield R. A. Tuna F. Wernsdorfer W. Winpenny R. E. P. Sulway,
Floriana Tuna,
Wolfgang Wernsdorfer,
Richard E. P. Winpenny,
R. A. Layfield F Tuna W Wernsdorfer and R. E. P. Winpenny S. Sulway
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Abstract
[Cp2Dy(thf)(mu-Cl)](2) (2) was synthesized from [Cp2Dy(mu-Cl)](n), which crystalizes as two polymorphs, with n = 2 (1a) or infinity (1b). All three compounds show slow relaxation of magnetization, and in 2 the quantum tunnelling was found to be exchange-biased.