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Royal Society of Chemistry, Dalton Transactions, 8(43), p. 3035-3038, 2014

DOI: 10.1039/c3dt52337c

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Fast magnetic relaxation in an octahedral dysprosium tetramethyl-aluminate complex

Journal article published in 2013 by Sonja N. König, N. F. Chilton C Maichle-Mössmer E Moreno-Pineda T Pugh R Anwander R A. Layfield* S. N. König, Nicholas F. Chilton Cäcilia Maichle-Mössmer Eufemio Moreno Pineda Thomas Pugh Reiner Anwander and Richard A. Layfield Sonja N. König, Nicholas F. Chilton ORCID, Cäcilia Maichle-Mössmer, Eufemio Moreno Pineda ORCID, Thomas Pugh ORCID, Reiner Anwander, Richard A. Layfield ORCID
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This paper is available in a repository.

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Abstract

Ab initio calculations on the octahedral dysprosium aluminate complex [Dy(AlMe4)3] (1) predict weak SMM properties. Dynamic magnetic susceptibility measurements on 1 confirm the theoretical predictions, revealing fast relaxation of the magnetization via quantum tunnelling.