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Royal Society of Chemistry, CrystEngComm, 46(15), p. 9878, 2013

DOI: 10.1039/c3ce41353e

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Solid state photodimerisation of tetrathiafulvalene derivatives bearing carboxylate and carboxylic acid substituents

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This paper is available in a repository.

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Abstract

Structural and spectroscopic studies on the [2+2] photodimerisation of TTF derivatives show that solid state cycloaddition leads to a dimer with a face-to-face structure. The type of phototransformation of the material depends not only on the optical characteristics of the reactant but also on those of the product.